Artículos de investigación / Research papers

-Papers 2022-

-Green AOT Reverse micelles as nanoreactors for Alkaline Phosphatase. The hydrogen bond “dances” between water and the enzyme, the reaction product, and the reverse micelles interface. Gustavo A. Monti, R. Darío Falcone, Fernando Moyano, N. Mariano Correa. RSC Advances.  En prensa 2022

-Gustavo A. Monti, Luis F. Berrio Velasco, Gustavo F. Silbestri, Patricia G. Molina, Fernando Moyano “Gold nanoparticles stabilized by sulfonated imidazolium salt for the manufacture of modified electrodes. Electrochemical detection of indomethacin”, Microchem J. 183 (2022) 107992

- A simple electrochemical immunosensor for sensitive detection of transgenic soybean protein CP4-EPSPS in seeds. M. E. Farías, N. M. Correa, L. Sosa, A. M. Niebylski, P. G. Molina. Talanta, 2022, 237, 122910

- Amphiphilic ionic liquids capable to formulate organized systems in an aqueous solution, designed by a combination of traditional surfactants and commercial drugs" Nahir Dib, Juana J. Silber, N. Mariano Correa, R. Dario Falcone. Pharmaceutical Research 2022, 10, 2379-2390

- How the type of interface can alter the behavior of an aprotic ionic liquid-water mixture entrapped in different reverse micelles. An exploratory study using an enzymatic reaction as a sensor Diana Blach, Valeria R. Girardi, Juana J. Silber, N. Mariano Correa, R. Dario Falcone. Colloids and Surface A 2022, 652, 129812. DOI

- Understanding the interfacial properties of bmim-AOT reverse micelles for their application as nanoreactors Cristian M. O. Lépori, M. Soledad Orellano, N. Mariano Correa, Juana J. Silber and R. Darío Falcone Journal of Molecular Liquids 2022, 366, 120238

- Ionic liquid-based reverse micelles. Use of hydrogen-deuterium exchange as a tool for surfactant self-assembly characterization. Nahir Dib, R. Darío Falcone, Ángel Acuña,  Luis García-Río. Journal of Molecular Liquids 2022, 365, 120039

-Carrier in carrier: Catanionic vesicles based on amphiphilic cyclodextrins complexed with DNA as nanocarriers of doxorubicin. Alarcón, L.P., Andrada, H.E., Olivera, M.E., Fernando Silva, O., Dario Falcone, R. Journal of Molecular Liquids, 2022, 360, 119488.

-Highly Stable Nanostructured Magnetic Vesicles as Doxorubicin Carriers for Field-assisted Therapies. Andrada, H.E., Venosta, L., Jacobo, S.E., ...Darío Falcone, R., Bercoff, P.G. ChemNanoMat, 2022, 8(4), e202100409.

-Production of Pd nanoparticles in microemulsions. Effect of reaction rates on the particle size. Sánchez M., J.F., Sánchez, M.D., Falcone, R.D., Ritacco, H.A. Physical Chemistry Chemical Physics, 2022, 24(3), pp. 1692–1701.

-Papers 2021-

Is it necessary for the use of fluorinated compounds to formulate reverse micelles in a supercritical fluid? Searching the best cosurfactant to create “green “ AOT reverse micelle media. J. A. Gutierrez*, M. L Japas, J. J. Silber, R. D Falcone, N. M Correa * Langmuir 2021. 37, 445-453. DOI 10.1021/acs.langmuir.0c03093.

New Insights into the Catalytic Activity and Reusability of Water-Soluble Silver Nanoparticles. G. A. Monti, N. M. Correa, R. D. Falcone, G. F. Silbestri, F. Moyano. ChemistrySelect, 2021, 6, 7436-7442.

Spectroscopic Characterization and General Features of Piroxicam Encapsulated in Nanostructured Lipid Carriers. J. Otarola*, P. G. Molina, M Garrido, N. Mariano Correa*. Colloids and Surface A. 2021, 616, 126340. DOI 10.1016/j.colsurfa.2021.126340.

Modified Reverse Micelle Method as Facile Way to Obtain Several Gold Nanoparticle Morphologies” J. A. Gutierrez*, J. J. Silber, R. D. Falcone, N. M. Correa. Journal Molecular Liquid 2021, 331 115709. DOI /10.1016/j.molliq.2021.115709.

Biocompatible Solvents and Ionic Liquids Based Surfactants as Sustainable Components to Formulate Environmentally Friendly Organized Systems” Nahir Dib, Cristian M. O. Lépori, N. Mariano Correa, Juana J. Silber, R. Dario Falcone, Luis García-Río. Polymers 2021 13, 1378. MDPI Switzerland, ISSN 2073-4360. DOI 10.3390/polym13091378.

How the External Solvent in Biocompatible Reverse Micelles Can Improve the Alkaline Phosphatase Behavior. N. Dib, V.R. Girardi, J. J. Silber, N. M. Correa, R. D. Falcone. Organic and Biomolecular Chemistry 2021, 19, 4969-4977. DOI 10.1039/D0OB02371J

Monitoring the microenvironment inside polymeric micelles using the fluorescence probe 6-propionyl-2-dimethylaminonaphthalene (PRODAN)  M. S. Orellano, D. A Chiappetta, J. J. Silber, R. D Falcone, N.M Correa. J. Mol. Liq. 2021, 343, 117552. DOI

Deciphering Solvation Effects in Aqueous Binary Mixtures by Fluorescence Behavior of 4-aminophthalimide: The Comparison Between Ionic Liquids and Alcohols as Cosolvents. M. A. Crosio, J.J. Silber, F.E. Moran Vieyra, R. D. Falcone, C.D. Borsarelli, N.M. Correa*. J. Phys. Chem B. 2021, 125, 13203-13211. DOI 10.1021/acs.jpcb.1c06569.

A comparative study of antimicrobial activity of differently-synthesized chitosan nanoparticles against bovine mastitis pathogens. M. S. Orellano, L. P. Bohl, M. L. Breser, P. Isaac, R. D. Falcone, C. Porporatto, Soft Matter. 2021, 17, 694-703.

Production of Pd Nanoparticles in Microemulsions. Effect of Reaction Rate on Particle Size. J. F. Sánchez M, M. D Sanchez, R. D. Falcone and H. A. Ritacco. Phys. Chem. Chem. Phys., 2021, en prensa

-Papers 2020-

Water-soluble gold nanoparticles: Recyclable catalysts for the reduction of aromatic nitro compounds in water. G. A. Monti, N. M Correa, R. D Falcone, G. Silbestri, F. Moyano. RSC Adv., 2020, 10, 15065–15071. DOI: 10.1039/d0ra02131h

Polyclonal Antibody Production Anti Pc_312-324 peptide. Its Potential Use in Electrochemical Immunosensors for Transgenic Soybean Detection. 
M. Farias, Mariela Marioni, Dario C. Ramirez, A. Niebylski, N. Mariano Correa, P.G. Molina. Bioelectrochemistry 2020, 131, 107397. Elsevier (Holanda) ISSN:1567-5394.

Piroxicam-Loaded nanostructured Lipid Nanocarriers Modified with Salicylic Acid: The effect on Drug Release. 
J J. Otarola, A. K. Cobo Solis, N.M. Correa, ¨P. G. Molina. ChemistrySelect 2020, 5, 804-809. WILEY-VCH. Alemania. ISSN: 2365-6549.

Catanionic Nanocarriers as a Potential Vehicle for Insulin Delivery. 
A. Stagnoli, L. Sosa Alderete, M. A. Luna, E. Agostini, R. D. Falcone, A.M. Niebylski, N.M. Correa. Colloids Surf B 2020, 188, 110759. DOI/10.1016/j.colsurfb.2019.110759.

Role of micellar interface in the synthesis of chitosan nanoparticles formulated by reverse micellar method” M. Soledad Orellano, Gabriel S. Longo, Carina Porporatto, N. Mariano Correa, R. Darío Falcone. Colloids and Surfaces A. 2020, 599 124876.

The ionic liquid-surfactant bmim-AOT and nontoxic lipophilic solvents as components of reverse micelles alternative to the traditional systems. A study by 1H NMR spectroscopy. N. Dib, R. D. Falcone, A. Acuña, L. García-Río. Journal of Molecular Liquids2020, 304, 112762, 1-8.

Characterization of Anionic Reverse Micelles Formulated on Bio-based Solvents as Replacing Conventional Non-polar Organic Solvents. 
M. Oyarzun, G. Oliva, R. D. Falcone, P. Pavez. ACS Sustainable Chem. Eng., 2020, 8, 14, 5478-5484.

Noscapine Loaded Nanostructured Lipid Carriers as a Potential Topical Delivery
. Alemania. ISSN: 2365-6549. Bovine Mastitis Treatment. J. Otarola, M. A. Luna, N. M. Correa, P. G. Molina. ChemistrySelect 2020, En prensa. DOI:10.1002/slct.202001138


Imim-DEHP reverse micelles investigated with two molecular probes reveals how are the interfacial properties and the coordination behavior of the surfactant.” Nahir Dib, Juana J. Silber, N. Mariano Correa, R. Dario Falcone. J Mol Liq 2020,313,113592. DOI: 10.1016/j.molliq.2020.113592.


Amphiphilic ionic liquids as sustainable components to formulate promising vesicles to be used in nanomedicine. R. D Falcone, N. M. Correa, J. J. Silber. Current Opinion in Green and Sustainable Chemistry 2020, 26:100382. DOI 10.1016/j.cogsc.2020.100382


Influence of the AOT counterion chemical structure in the generation of organized systems. Cristian M. O. Lépori, N. Mariano Correa, Juana J. Silber, R. Darío Falcone, Manuel López-López and M. Luisa Moyá. Langmuir 2020, 36, 10785-10793. DOI: 10.1021/acs.langmuir.0c01575.


Spontaneous formation of unilamellar vesicles based on the surfactant 1-methylimidazolium bis-(2-ethylhexyl) phosphate, evaluated as a function of pH and in saline solution. Heber E. Andrada, O. Fernando Silva, Gustavo M. Morales, N. Mariano Correa and R. Dario Falcone. Colloids and Suface A. 2020, 125435. DOI. 10.1016/j.colsurfa.2020.125435


Understanding metallic nanoparticles stabilization in water by imidazolium salts. A complete physicochemical study. G. A. Monti, N M Correa, R. D. Falcone, G. F. Silbestri, F. Moyano. ChemistrySelect 2020, 5, 11264-1171. DOI 10.1002/slct.202002869.

                                                                                 -Papers 2019-

Gold Nanoparticle Stabilized by Sulfonated-Imidazolium Salts as Promising Catalyst in water. G.A. Monti, N. M. Correa, R. D. Falcone, G. F. Silbestri, F. Moyano. ChemSelect 2019, 4, 13496-13502 . WILEY-VCH. Alemania. ISSN: 2365-6549. DOI: 10.1002/slct.201903396.

Use of ionic liquids-like surfactants for the generation of unilamellar vesicles with potential applications in biomedicine. C. M. O. Lépori, N. M. Correa, J. J. Silber, R. D. Falcone, M. López-López, M. L. Moyá. Langmuir 2019, 35, 13332−1339. DOI: 10.1021/acs.langmuir.9b01197.

Electrochemical Methodology as an Useful Tool for the Interfacial Characterization of Aqueous Reverse Micelles A.K. Cobo Solis, M. A. Luna, R. D. Falcone, N. M Correa*, P. G. Molina* ChemistrySelect 2019, 4, 14309– 14314. WILEY-VCH. Alemania. ISSN: 2365-6549. DOI: 10.1002/slct.201903904

Supramolecular systems as an alternative for enzymatic degradation of 1-naphthyl methylcarbamate (Carbaryl) pesticide. E. I. Gomez Rodríguez, R. D. Falcone, P. R. Beassoni, F. Moyano, N. M. Correa. ChemistrySelect2019, 4, 7204-7210. DOI: 10.1002/slct.201901735

Combination of protic ionic liquid-like surfactant and biocompatible solvents to generate environmentally friendly anionic reverse micelles. N. Dib, J. J. Silber, N. M. Correa, R. D. Falcone. New J. of Chemistry, en prensa 2019, DOI: 10.1039/C9NJ02268F.

Interfacial Dynamics and its relations with "negative" surface viscosities measured at water-air interfaces covered with a cationic surfactant. V. E. Cuenca, M. Fernández-Leyes, R. D. Falcone, N. M. Correa, D. Langevin, H. A. Ritacco. Langmuir, en prensa 2019. DOI: 10.1021/acs.langmuir.9b00534.

Vehiculization of noscapine in large unilamellar vesicles. Study of its protective role against lipid peroxidationby electrochemical techniques. M. A. Luna, J.A. Gutierrez, A.K. Cobo Solis, P. G. Molina, N. M. Correa. Journal of Electroanalitical Chem. 2019. 833, 26-32 

Interfacial properties modulated by the water confinement in Reverse Micelles created by the Ionic Liquid-like surfactant bmim-AOT. Cristian M. O. Lépori, N. Mariano Correa, Juana J. Silber, Fabián Vaca Chávez*, R. Darío Falcone. Soft Matter, 2019, 15, 947-955.

Catanionic Reverse Micelles as an Optimal Microenvironment To Alter the Water Electron Donor Capacity in a SN2 Reaction. Cristian C. Villa, N. Mariano Correa, Juana J. Silber, R. Dario Falcone. J. Org. Chem. 2019, 84, 1185−1191.

Chitosan nanoparticles enhance the antibacterial activity of the native polymer against bovine mastitis pathogens. M. S. Orellano, P. Isaac, M. L. Breser, L. P. Bohl, A. Conesa, R. D. Falcone, C. Porporatto. Carbohydrate Polymers 213 (2019) 1–9.

                                                                                     -Papers 2018-

Study of Lipid Peroxidation and Ascorbic Acid Protective Role in Large Unilamellar Vesicles from a New Electrochemical Performance. M. F. Barroso, M. A. Luna, F. Moyano, C. Delerue-Matos, N. M Correa, P. G. Molina. Bioelectrochemistry. 2018, 120, 120–126.

Characterization of a label system formed by large unilamellar vesicles for its potential use in the design of electrochemical biosensors. M. Farías, M. A. Luna, A. M. Niebylski, N. M. Correa, P.G. Molina. Microchemical Journal. 2018 140, 105–113. 

Micropolarity and hydrogen bond donor ability of environmentally friendly anionic reverse micelles, explored by UV-visible absorption of a molecular probe and FT-IR spectroscopies. V. R. Girardi, J. J. Silber, R. Darío Falcone, N. Mariano Correa. ChemPhysChem, 2018, 19, 759-765.

Spontaneous catanionic vesicles formed by the interaction between an anionic β-cyclodextrins derivative and a cationic surfactant. O. Fernando Silva, Rita H. de Rossi, N. Mariano Correa, Juana J. Silber R. Darío Falcone, RSC-Advances, 2018, 8, 12535–12539.

Structural Characterization of Biocompatible Reverse Micelles using Small-Angle X-Ray Scattering, 31P Nuclear Magnetic Resonance and Fluorescence Spectroscopy. Emmanuel Odella, Ruben Dario Falcone, Marcelo Ceolin, Juana J. Silber, N. Mariano Correa. J. Phys. Chem. B, 2018, 122, 4366–4375.

Structural Characterization of Biocompatible Reverse Micelles using Small-Angle X-Ray Scattering, 31P Nuclear Magnetic Resonance and Fluorescence Spectroscopy. Emmanuel Odella, Ruben Dario Falcone, Marcelo Ceolin, Juana J. Silber, N. Mariano Correa. J. Phys. Chem. B, 2018, 122, 4366–4375.

-Papers 2017-

On the Design of a Versatile Ionic Liquid, AOBH-DEHP, which Can Be Used As a New Molecular Probe to Investigate Supramolecular Assemblies. Matías A. Crosio, Juana J. Silber, R. Darío Falcone, N. Mariano Correa Dyes and Pigments 2017, 138, 68-76.

Unique Catanionic Vesicles as a Potential “Nano-Taxi” for Drug Delivery System. In Vitro and In Vivo Biocompatibility Evaluation. S. Stagnoli; M. A. Luna; C. C. Villa; F. Alustiza, A. Niebylski; F. Moyano; N. M. Correa, R. D. Falcone. RSC Adv., 2017, 7, 5372–5380.

The Use of AOBH-DEHP Molecular Probe to Characterize BHDC Reverse Micelles Interfaces. Insights on the Interfacial Water Structure. M A. Crosio, J. J. Silber, F. Moyano, N. M. Correa, R. D. Falcone. ChemistrySelect, 2017, 2, 2880-2887.

AOT Reverse Micelles as versatile reaction media for chitosan nanoparticles synthesis M. S. Orellano, C. Porporatto, J. J. Silber, R. D. Falcone, N. M Correa. Carbohydrate Polymers. 2017, 171, 85-93.

Gold Nanoparticles Stabilized with Sulfonated Imidazolium Salts in Water and Reverse Micelles. G. A. Monti, G.A. Fernández, N. M. Correa; R. D. Falcone, F. Moyano, G. F. Silbestri R. Soc. open sci. 2017, 4, 170481

Subtleties of Catanionic Surfactant Reverse Micelle Assemblies Revealed by a Fluorescent Molecular Probe. C. C. Villa, J. J. Silber, R. D. Falcone, N. M. Correa.  Methods Appl. Fluoresc. 2017, 5, 044001.

Improvement of the Amphiphilic Properties of a Dialkyl Phosphate by Creation of a Protic Ionic Liquid-like Surfactant. C. M. O. Lepori, J. J. Silber, R. D. Falcone, N. M. Correa. RSC Adv., 2017, 7, 44743–44750.

Determination of Benzyl- hexadecyldimethylammonium 1,4-bis (2-ethylhexyl) Sulfosuccinate Vesicles Permeability by Using Square Wave Voltammetry and an Enzymatic Reaction A. K. Cobos Solis, N. M. Correa, P.G. Molina Langmuir 2017, 33, 12080−12086. 

-Papers 2016-

Determining the substrate permeability through the bilayer of large unilamellar vesicles of DOPC. A kinetic study. M. Alejandra Luna, Juana J. Silber, L. Sereno, N. Mariano Correa, Fernando Moyano. RSC Advances. 2016, 6, 62594 – 62601

Gold nanoparticles covalently assembled onto vesicle structures as possible biosensing platform. M. Fátima Barroso, M. Alejandra Luna, Juan S. Flores Tabares, Cristina Delerue-Matos, N. Mariano Correa, Fernando Moyano, Patricia G. Molina. Beilstein J. Nanotechnol., 2016, 7, 655-663

How the Type of Cosurfactant Impacts Strongly on the Size and Interfacial Composition in Gemini 12-2-12 RMs Explored by DLS, SLS, and FTIR Techniques. Victor E. Cuenca, R. Darío Falcone, Juana J. Silber, and N. Mariano Correa. J Phys. Chem. B, 2016, 120, 467-476.

A protic Ionic Liquid, when Entrapped in Cationic Reverse Micelles, Can Be Used as Suitable Solvent for a Bimolecular Nucleophilic Substitution Reaction. Matias A. Crosio, N. Mariano Correa, Juana J. Silber, R. Darío Falcone. Organic & Biomolecular Chemistry, 2016, 14, 3170-3177.

Effect of the Confinement on the Properties of Mixed Polar Solvents Sequestrated. The case of Enzymatic Catalysis Performed in Nonaqueous AOT Reverse Micelle. Andrés M. Durantini, R. Darío Falcone, Juana J. Silber, N. Mariano Correa. ChemPhysChem. 2016, 17, 1678 – 1685

Square Wave Voltammetry: An Alternative Technique to Determinate Piroxicam Release Profile from Nanostructured Lipid Carriers. 
Jessica Otarola, Mariano Garrido, N. Mariano Correa, Patricia G. Molina. ChemPhysChem, 2016, 17, 2322-2328

Electrochemical and Photophysical Behavior of 1-Naphthol in Benzyl-n-hexadecyldimethylammonium 1,4-bis (2-ethylhexyl) Sulfosuccinate Large Unilamellar Vesicles. 
Airam K. Cobo Solis, N. Mariano Correa, Patricia G. Molina. PhysChemChemPhys, 2016, 18, 15645-15653.

Nanoscale Control Over Interfacial Properties in Mixed Reverse Micelles Formulated Using Sodium 1,4-bis-2-ethylhexylsulfosuccinate and Tri-n-octyl Phosphine Oxide Surfactants.
 Emmanuel Odella, R. Dario Falcone, Juana J. Silber, N. Mariano Correa. ChemPhysChem. 2016, 17, 2407-2414.

Properties of AOT reverse micelle interfaces with different polar solvents.
 M. Alejandra Luna, N. Mariano Correa, Juana J. Silber, R. Dario Falcone, Fernando Moyano. Journal of Physical Organic Chemistry, 2016, 29, 580-585.

How the cation 1-butyl-3-methylimidazolium impacts on the interaction between the entrapped water and the reverse micelle interface created with an ionic liquid-like surfactant. C. Lépori, N. M. Correa, J. J. Silber, R. D. Falcone. Soft Matter, 2016, 12, 830-844.  

Non-aqueous Reverse Micelles Created with a Cationic Surfactant: Encapsulating Ethylene Glycol in BHDC/nonpolar solvent blends. F M. Agazzi, R. D. Falcone, J. J. Silber, N. M. Correa. Colloids and Surfaces A 2016, 509,467-473. 

Capítulos en libros / Chapters in books
Ionic Liquids in Soft Confinement. Effect of the Different Reverse Micelles Interfaces on the Entrapped Ionic Liquid Structure. R. D. Falcone, N. M. Correa, N. E. Levinger, J. J. Silber Capitulo del libro Ionic Liquid-Based Surfactant Science: Formulation, Characterization and Applications, Eds. Bidyut K. Paul and Satya P. Moulik, John Wiley & Sons Inc., USA. ISBN-10: 1118834194. ISBN-13: 9781118834190. 2015, 283-301.

Electro-optics and Electroporation of Synthetic Lipid Vesicles Z A Schelly, N. Asgharian, N. M. Correa, V. Peikov, S. Wu, H. Zeng, H. Zhang in Molecular and Colloidal Electro-optics," Capitulo 12 edited by Professors S. P. Stoylov and M. Stoimenova; CRC Press, Boca Raton, FL ISBN: 0-8493-9811-8 paginas 301-306. (2006).

Reactividad y Catálisis en Micelas Inversas. M.A. Biasutti, N.M. Correa, J.J. Silber.. under the sponsorship of IUPAC (Project 2002-064-1-300)- and INCA-Italy. Eds Rita H. de Rossi and Pietro Tundo- ISBN 88-88214-16-X. Química Verde en Latinoamerica. GREEN CHEMISTRY SERIES 239-258 (2004).

Solubilización y Reactividad en Soluciones Organizadas. N. Mariano Correa, M.A. Biasuti, J.J. Silber. Capítulo de libro Química Sustentable por invitación Editor: N. Nudelman. UNL. ISBN. 987-508-243-0. 269-294 (2004).

Study of Different Molecular Probes in Nonaqueous AOT Reverse Micelles. R.D. Falcone, N. Mariano Correa, M.A. Biasutti, J.J. Silber. Capítulo de libro de First- Italia-Argentina Workshop on Green Chemistry. Green Chemistry Series N 8. Eds G. Cerichelli, P. Tundo INCA. 71, ISBN 88-88214-03-8. Pag.71 – 73. (2003). 

Molecular Interactions in Reverse Micelles. M. A. Biasutti, N.M. Correa, J.J. Silber. Current Topics in Colloid and Interface Science. Research Trends. India Eds. F.M. Goñi, H. Hoffmann. Vol. 3, 35-51. ISBN 81-258-0045-X. (1999).